Stronger Plastics and Better Anti-Glare Coatings: Exploring the Properties of a Fluorinated CBDO Structure
dc.contributor.advisor | Booth, Chad | |
dc.contributor.author | Lynch, Jonathan | |
dc.date.accessioned | 2017-09-13T18:38:11Z | |
dc.date.available | 2017-09-13T18:38:11Z | |
dc.date.issued | 2013-05 | |
dc.description.abstract | Exciting advances have been made in recent years regarding both polymers that incorporate fluorine atoms or groups and polymers that incorporate 2,2,4,4-tetramethyl-1,3-cyclobutanediol (CBDO) based monomers into their backbone. A wide range of polymers have incorporated fluorine into their systems, usually in the form of trifluoromethyl (-CF3) groups. These groups increase the thermal and thermooxidative stability, flame resistance, mechanical stability, and optical transparency. The latter, especially, makes these systems optimal for anti-glare coatings for eyeglasses, military and commercial aircraft windows, and spacecraft windows. Incorporating trifluoromethyl groups into a polymer system via a cyclic structure opens the door to the potential for some particularly exciting properties, especially those of mechanical and thermal stability. A process for the preparation of the novel compound 2,2,4,4-tetrakis(trifluoromethyl)cyclobutane-1,3-diol (F12-CBDO) is described. Polymers incorporating this new monomer were expected to show superior mechanical and thermal stability, flame resistance, optical transparency, and other properties compared to their non-fluorinated counterparts. They were also expected to show superior properties compared to systems that did not incorporate a CBDO monomer at all. While successful synthesis of the F12-CBDO monomer was not achieved in the time constraints of this experiment, several considerations for future research concerning this monomer are discussed. | |
dc.description.department | Honors College | |
dc.format | Text | |
dc.format.extent | 28 pages | |
dc.format.medium | 1 file (.pdf) | |
dc.identifier.citation | Lynch, J. D. (2013). Stronger plastics and better anti-glare coatings: Exploring the properties of a fluorinated CBDO structure (Unpublished thesis). Texas State University-San Marcos, San Marcos, Texas. | |
dc.identifier.uri | https://hdl.handle.net/10877/6864 | |
dc.language.iso | en | |
dc.subject | organic | |
dc.subject | chemistry | |
dc.subject | Trifluoromethyl | |
dc.subject | coating | |
dc.subject | film | |
dc.subject | novel | |
dc.subject | polymer | |
dc.subject | CBDO | |
dc.subject | Honors College | |
dc.title | Stronger Plastics and Better Anti-Glare Coatings: Exploring the Properties of a Fluorinated CBDO Structure | |
thesis.degree.department | Honors College | |
thesis.degree.discipline | Chemistry and Biochemistry | |
thesis.degree.grantor | Texas State University-San Marcos | |
txstate.documenttype | Honors Thesis |